資源描述：
《electrochemistry at metal and semiconductor electrodes》由會員上傳分享，免費(fèi)在線閱讀，更多相關(guān)內(nèi)容在學(xué)術(shù)論文-天天文庫。
1、PREFACEElectrochemistryatElectrodesisconcernedwiththestructureofelectricaldoublelayersandthecharacteristicofchargetransferreactionsacrosstheelectrode/electrol}^interface.Thepurposeofthistextistointegratemodemelectrochemistrywithsemiconductorphysics;thisapproachprovidesa
2、quantitativebasisforunderstandingelectrochemistryatmetalandsemiconductorelectrodes.Electronsandionsaretheprincipalparticlesthatplaythemainroleinelectrochemistry.Thistext,hence,emphasizestheenergylevelconceptsofelectronsandionsratherthanthephenomenologicalthermodynamican
3、dkineticconceptsonwhichmostoftheclassicalelectrochemistrytextsarebased.ThisrationaUzationofthephenomenologicalconceptsintermsofthephysicsofsemiconductorsshouldenablereaderstodevelopmoreatomisticandquantitativeinsightsintoprocessesthatoccuratelectrodes.Thisbookincorporat
4、esintomanytraditionaldisciphnesofscienceandengineeringsuchasinterfacialchemistry,biochemistry,enzymechemistry,membranechemistry,metallurgy,modificationofsoUdinterfaces,andmaterialscorrosion.Thistextisintendedtoserveasanintroductionforthestudyofadvancedelectrochemistryat
5、electrodesandisaimedtowardsgraduatesandseniorundergraduatesstudyingmaterialsandinterfacialchemistryorthosebeginningresearchworkinthefieldofelectrochemistry.Chapter1introducesaconceptofenergylevelsofparticlesinphysicochemicalensembles.ElectronsareFermiparticleswhoseenerg
6、ylevelsaregivenbytheFermilevels,whileionsareBoltzmxinnparticleswhoseenergyisdistributedinanexponentialBoltzmannfunction.InChapter2theenergylevelsofelectronsinsolidmetals,solidsemiconductors,andaqueoussolutionsarediscussed.Electronsinmetalsareindelocalizedenergybandsele
7、ctronsinsemiconductorsareindelocahzedenergybandsaswellasinlocaUzedlevels;andredoxelectronsassociatedwithredoxparticlesinaqueoussolutionsareinlocalizedlevelswhicharesplitintooccupied(reductant)andvacant(oxidant)electronlevelsduetotheFranck-Condonprinciple.Chapter3introdu
8、cestheenergylevelsofionsingas,liquid,andsolidphases.Inaqueoussolution,theacidicandbasicprotonlevelsinwatermole
