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1、摘要ChemicalStabilizationofMercurycontaminatedSoilsAbstractMercurycontaminationinsoilsisincreasinglyunderenvironmentalconcern,asaresultofitshighhighlytoxic,persistentandbioaccumulation.Theprincipleofthechemicalstabilizationusedinsoilremediationisthatmerc
2、urycontaminatedinsoilstransformtothemoststablecompoundinsoils,byartificialmeansofchemicalstabilizers.Chemicalstabilizationiswidelyusedforremediationofsoilsduetochemicalreactionsandphysicalreactions.Inthispaper,Mercuryinsoilstransformintomercuricsulfide
3、whichisSOstablethatcanbeexistedinthesoilwithalongtime,becauseofchemicalstabilizationrepairtechniques.Moreover,themobilityandtoxicityofmercuryinsoiliSbecome10W.Evaluationofstabilizationofmercuryinsoilswasconductedbyinapartofexperiment.Ithasbeenindicated
4、thatTriticumaestivummainlyabsorbedthewatersolubleandexchangeablefractionofHgandboundtoironandmanganeseoxidesfractionHginsoils.Inaddition,Triticumaestivumisabletoabsorblittleofboundtocarbonatesfractionofrig,boundtoorganicmatterIII北京化工大學碩士學位論文fractionofH
5、gandresidualfractionofriginsoils.Theresultsworkasoneoftheefficientevaluationofstabilizationofmercuryinsoils.Insinglefactorexperimentsandorthogonalexperimentofstabilizationofmercuryinsoils,thethreefactorsarepH,amountofstabilizerandamountoforganicmatters
6、.Accordingtotheresultsofstabilityefficiency,bioavailabilityandleachingtoxicityefficiency,thebestconditionofstabilizationisS:H927,4.62%(organicmatterscontent),andpH6.KEYWORDS:soils,mercury,chemicalstabilization,sodiumsulfide,evaluationofstabilization,sp
7、eciationanalysis,leachingtoxicityIV目錄第一章緒論??????????????????????????????.11.1汞的來源及環(huán)境化學特征???????????????.11.2汞污染的危害及土壤治理必要性???????????..?..21.3汞在土壤中的存在形態(tài)及遷移轉(zhuǎn)化規(guī)律???????????.31.3.1汞在土壤中的存在形態(tài)???????????????.31.3.2汞在土壤中的遷移轉(zhuǎn)化規(guī)律??????????????51.4生物對汞的吸收特性一固定效
8、率評價????????????.71.4.1指示植物的選取???????..?.????????.71.4.2汞對生物的吸收特性研究進展?????????????.81.5汞污染土壤穩(wěn)定化概述????????????????91.5.1汞污染治理方法概述????????????????91.5.2化學穩(wěn)定化研究現(xiàn)狀???????????????..101.6穩(wěn)定效率評價??????????????????.121.6.1穩(wěn)定效率表達方式一形態(tài)分析法??????????