納米晶鎂合金表面化學(xué)鍍ni-p合金鍍層的分析

納米晶鎂合金表面化學(xué)鍍ni-p合金鍍層的分析

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時(shí)間:2019-02-01

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1、太原理工大學(xué)碩士研究生學(xué)位論文resistanceofNi—Pcoating.Thethesisfocusedontheoptimumprocesstoobtainthefavourablecoatingofmorphology,uniformthickness,wearandcorrosionresistanceproperties.Tilematrixgrainweretessellatedanddefectswerereduced,SOthatthequalitywasenhancedandcorrosionresistaneeofNi—Pc

2、oatingonmagnesiumalloycouldbeimprovedthroughnano—processonthesurfaceofmagnesiumalloy.Inaddition,thepaperstudiedtheinfluenceofthermaltreatmentontheNi—PcoatingofNanocrystallinemagnesiumalloy.Basedonthestudies,themainconclusioncanbedrownasfollows:1、Theoptimaltechnologicalschemeof

3、electrolessplatingwhichwascheapandsimplewasconfirmedfrommultipleexperiments.NiS04’6H20NaH2P02’H20CH3COONaNH4HFHF(40%)thiocarbamidePH16g/L;14g/L;13g/L;8g/L;12ml/L;0.001g/L;6.4±O.2:Temperature:80±2℃。2、Thr。ughthisl(i11d。ftecllll。1。giJIllscheme,thetypicalcellularstructurecouldbeob

4、tainedwithcompactanduniformcoatingbutnoobviousdefect(averagein20—30Ⅲm)Ni—Pplatingwasphosphoruscoatingwithphosphorus。V】太原理工大學(xué)碩士研究生學(xué)位論文contentwasbetween5%and8%.3、Comparedtothecoarse—grainedmagnesiumalloy,theplatingrateonnanocrystallinewasslowerinmagnesiumalloysurfaceelectrolessp

5、latingwhichwastreatedbymeansofnano.Thereasonwasthatnanocrystallinemagnesiumalloyownthebiggerspecificsurfaceareaandencounteredmoreresistanceinstageofsurfacenucleation.Whereasinthenucleationstage,theactivationpointandplatingrateofnanocrystallinemagnesiumalloygotmore,coatingthick

6、nesswasalsogreat.4、ThehardnessoftheNi—Pcoatingonthesurfaceofmagnesiumalloywasreachedto427HVwhereasthecoatingonthenanocrystallinecouldbeattainedto689HVBymeansofthermaltreatment.thehardnessofthecoatingwaspromotedfurtheron.Especiallywhenthetemperaturewas300。C,itcouldbereachedto13

7、0HV.Thewear—resistingperformanceofthecoatingcouldbepromotedthroughthehardness.Moreover,thefrictioncoefficientisdecreaseslightly.5、Thecorrosionresistanceofmagnesiumalloycouldbereducedbynanocrystalline,butitonNi—Pcoatingwasincreased.Thecorrosionresistanceofcoatingdepressedaftert

8、hermaltreatment.Meanwhile,itgotworseandworseinthewakeoftemper

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