元素周期表歷史

元素周期表歷史

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時間:2019-02-03

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1、OrganizationoftheElements:ThePeriodicTable,asweknowit,wasnotsomethingthatwas“stumbledupon.”Ithasbeendeveloped,modified,andimprovedforthelast200years.Bytheeighteenthcentury,chemistsrealizedthateachelementhadacharacteristicmass.Thus,theyusedmassastheirbasisfor

2、organizationoftheelements.In1817,JohannD?bereinerofGermanywasoneofthefirsttoformallyorganizetheelements.Hegroupedelementsinthreesbasedontheirsimilardifferencesinatomicmass.Hecalledthegroupsofthreetriads.Thesetriadshadsimilarchemicalandphysicalproperties.Ex-E

3、lementMassDMassProperties16.1lithium6.9Soft,16.1sodium23.0veryreactivepotassium39.1metals.44.4Ex-chlorine35.5Coloured,47.0bromine79.9veryreactiveiodine126.9non-metals.However,D?bereiner’s“LawofTriads”wasfoundtobemerelyacoincidence.By1829,80%oftheelementsknow

4、ndidnotfitintoatriad!ThenextmajordevelopmentinthePeriodicTablebeganin1864withtheBritishchemist,JohnNewlands.Hearrangedtheknownelementsinorderofincreasingatomicmass.Newlandsfoundthateveryeighthelementhadsimilarchemicalandphysicalproperties.Sincethepatternwasi

5、neights,Newlands’sdiscoverywascalledthe“LawofOctaves.”Unfortunately,thismethodoforganizationonlyworkedforthefirst20elements.Asmoreelementswerediscovered,theLawofOctavesfailedbecausethepropertiesbecameinconsistent.Forexample,thereactivemetalsLi,Na,K,Rb,andCsw

6、eregroupedwiththenon-reactivemetalsCu,Ag,andAu.Asaresultofthisfailure,improvementscameaboutveryrapidly.In1869,aRussianchemistDmitriMendeléevproposedthefollowinghypothesis,knownasMendeléev’sPeriodicLaw:“Thepropertiesoftheelementsareperiodicfunctionsoftheirrel

7、ativeatomicmasses.”Althoughhehadthislaw,Mendeléevdidnotrestricthimselftopatternsofeight;heincludedsub-groups.Mendeléevalsohadtheforesighttounderstandthatitwaspossiblesomeelementshadnotyetbeendiscovered.Soifhedecidedthatthenextheaviestelementdidnothavepropert

8、iesthatallowedittofitwithinthenextgroup,buthadpropertiesthatmadeitfitbetterinafollowinggroup,heleft“blanks.”Hedecidedthatelementsthatwouldfilltheblankswouldbediscoveredlater–HEWASRIGHT!Forexampl

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