資源描述:
《硅納米線陣列的制備與光伏應(yīng)用的分析》由會員上傳分享,免費在線閱讀,更多相關(guān)內(nèi)容在行業(yè)資料-天天文庫。
1、———————————————』墮墮一AbstractPhotovoltaictechnologyisoneoftheeffectivewaystOsolvetheener譬y嘶SjsandenVlronmentalpollution。Atpresent,crystallinesiliconsolarcellsremaillthebastsofthecurrentphotovoltaicindustry.However,thehighcostofcrystallinesiltconsolarceJJ8hasg
2、reatlyhinderedthedevelopmentofthephotovoltaicindus魄Siliconnanowires(SiNWs)areconsideredaspromisingmaterialstoacbievehigheffictencⅥJowcOStsolarcells,duetotheirexcellentlightabsorbingpropertiesande伍cientcafTlerseparationperformance.Therefore,theresearchonsili
3、connanowirearravsforpnotoVoltaicapplicationsisverymeaningful.Inthispaper,t11eantirenectionpropertiesofSiNWsarray,solarcellperformance,aswellassu—hceDassivationofSiNWsarrayhasbeenresearched.Theresultsweobtainedareasfoilo、vS:(1)mSiNWsarraycanbecreatedbymetal.
4、assistedchemicaletching(MACE)astheAgnanoparticlesfilmverticallysink.Theleng_tllofSiNWsarrayscanberegulatedbyadjustingtheetchingtime.withetchingtimeforsiliconsubstrates,ThelengthsofSiNWsarmyincreaselinearlySiliconnanowirearrayshasalowreflectance(<1%)overawid
5、erange(300-1000nm).TheSiNWarraysoflongerlengthhaVeloWerreflectaIlcemourinvestigatedlengthrange.TheSiNWsolarcellexhibitsahigherpowerconversionefficiencyof8.84%thanthecellbasedonpolishedsiliconwafer,underthesameconditionofcompactcontactofthefrontsurfaceelecn.
6、ode.Wef-oundthatthereasonfortheincreaseofcellefficiency,inadditiontotheexcellentantireflectionpropertiesofSiNWsarrays,istheimprovedlong.wavelengthsunlightabsorptionwhichreducestherecombinationofminoritycarrier.(2)ThelengthoftheSiNWsarraysCanbemanipulatedbya
7、djustingtllereactiontime·FlaereflectancedecreaseswiththeSiNWs’lengthincreasing.Bvcombiningthermaloxidationandhydrofluoricacidtreatment,wecanmaIliDulatetllefillingratioofSiNWs.WiththeSiNWs’fillingratiodecreasing,therefleclancedecreasesatfirst,andthenincrease
8、s.Si/Si02coaxialnanowiresarraycanbeobtainedbythermaloxidationofas-grownSiNWsarray.Theresultsshowmat廿1esilicondioxideshellCannotonlyfurtherreducethereflectanceofSiNWsarray,butalsopasslVatesurfacestateso