硅納米線陣列的制備與光伏應(yīng)用的分析

硅納米線陣列的制備與光伏應(yīng)用的分析

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時間:2019-02-22

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1、———————————————』墮墮一AbstractPhotovoltaictechnologyisoneoftheeffectivewaystOsolvetheener譬y嘶SjsandenVlronmentalpollution。Atpresent,crystallinesiliconsolarcellsremaillthebastsofthecurrentphotovoltaicindustry.However,thehighcostofcrystallinesiltconsolarceJJ8hasg

2、reatlyhinderedthedevelopmentofthephotovoltaicindus魄Siliconnanowires(SiNWs)areconsideredaspromisingmaterialstoacbievehigheffictencⅥJowcOStsolarcells,duetotheirexcellentlightabsorbingpropertiesande伍cientcafTlerseparationperformance.Therefore,theresearchonsili

3、connanowirearravsforpnotoVoltaicapplicationsisverymeaningful.Inthispaper,t11eantirenectionpropertiesofSiNWsarray,solarcellperformance,aswellassu—hceDassivationofSiNWsarrayhasbeenresearched.Theresultsweobtainedareasfoilo、vS:(1)mSiNWsarraycanbecreatedbymetal.

4、assistedchemicaletching(MACE)astheAgnanoparticlesfilmverticallysink.Theleng_tllofSiNWsarrayscanberegulatedbyadjustingtheetchingtime.withetchingtimeforsiliconsubstrates,ThelengthsofSiNWsarmyincreaselinearlySiliconnanowirearrayshasalowreflectance(<1%)overawid

5、erange(300-1000nm).TheSiNWarraysoflongerlengthhaVeloWerreflectaIlcemourinvestigatedlengthrange.TheSiNWsolarcellexhibitsahigherpowerconversionefficiencyof8.84%thanthecellbasedonpolishedsiliconwafer,underthesameconditionofcompactcontactofthefrontsurfaceelecn.

6、ode.Wef-oundthatthereasonfortheincreaseofcellefficiency,inadditiontotheexcellentantireflectionpropertiesofSiNWsarrays,istheimprovedlong.wavelengthsunlightabsorptionwhichreducestherecombinationofminoritycarrier.(2)ThelengthoftheSiNWsarraysCanbemanipulatedbya

7、djustingtllereactiontime·FlaereflectancedecreaseswiththeSiNWs’lengthincreasing.Bvcombiningthermaloxidationandhydrofluoricacidtreatment,wecanmaIliDulatetllefillingratioofSiNWs.WiththeSiNWs’fillingratiodecreasing,therefleclancedecreasesatfirst,andthenincrease

8、s.Si/Si02coaxialnanowiresarraycanbeobtainedbythermaloxidationofas-grownSiNWsarray.Theresultsshowmat廿1esilicondioxideshellCannotonlyfurtherreducethereflectanceofSiNWsarray,butalsopasslVatesurfacestateso

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