低溫固化環(huán)氧粉末涂料與mdf粉末靜電噴涂工藝-研究

低溫固化環(huán)氧粉末涂料與mdf粉末靜電噴涂工藝-研究

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時(shí)間:2019-02-24

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1、萬方數(shù)據(jù)ABSTRACTThethermosettingpolymerpowderscoatingisundergoingrapidgrowthasallecological,economicandenergyefficienttechnology.PowdercoatingspossessadvantagesoverconventionalcoatingsinthatnOpollutingsolventlossoccursonapplication,flammabilityandtoxicityaresubstantial

2、lyreduced,owingtotheuseofelectrostaticspray,littlematerialislostand,whatismore,duringbaking,energyconsumptioncanbereducedcomparedtosolvent-borneorwater—bornecoatings.Inthispaper,twokindsofepoxypowdercoatingswerepreparedbymeltingblendingofphenolicresin/alkalineaccel

3、eratorandmicronizeddicyandiarnide(Dicy)/2-methylimidazole(2-MI)ascuringsystems.Thefactorsthataffectthecuringreactionandmechanicalpropertiesofepoxypowdercoatingswereinvestigated,suchasamountofcuringagentandaccelerator.Then,thecuringreactionandcuringkineticsofthistwo

4、differentsystemswereinvestigatedbynon-isothermaldifferentialscanningcalorimetry(DSC),andthecuringprocessWasdeduced.Atlast,theoptimumamountofthecuringsystemsandtheircuringconditionsweredetermined.Inaddition,theeffectofthetechnologicalparametersofelectrostaticsprayin

5、gformediumdensityfiberboard(MDF)ontheone-passtransferefficiencyofpowderwerediscussedbyresponsesurfaceanalysisandtheinfluencefactorsofcoatingflattingpropertywerestudiedpreliminarily.Theexperimentshowedthatfortheepoxy-phenolssystemtheoptimumamountsofphenolsandalkalin

6、eacceleratorwererespectively10%and1.0%.Forthissystemthebestcuringconditionswerecuring30minutesat120degreescentigrade.Andthecuredlayershadgoodmechanicalproperties.Withregardtotheepoxy—Dicysystem,theoptimumamountSofDicyand2-M1wererespectively2.5%andO.25%anditshouldbe

7、cured30minutesat130degreescentigrade.Asecondorderpolynomialempiricalmodelsoftheone-passtransferefficiencyofpowderwiththetechnologicalparametersofelectrostaticsprayingwassetupbyusingBox—Behnkenexperimentaldesigncombinedwithresponsesurfaceanalysis.Theeffectoftechnolo

8、gicalparametersontheone-passtransferefficiencyandtheirinteractionwerediscussed.Andtheoptimaltechnologicalparametersweredetermined.Withthespraying

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