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1、碳材料(部分)的微反應(yīng)體系姚月110924www.themegallery.comLOGO1234ContentsbackgroundMeso-porouscarbonmaterialsmicroreactor實(shí)驗(yàn)部分多孔材料Porouscarbonmaterialshavebeenappliedtogasseparation,waterpurification,catalystsupports,andelectrodesforelectrochemicaldoublelayercapacito
2、rsandfuelcells.AccordingtotheInternationalUnionofPureandAppliedChemistry(IUPAC)recommendation,porouscarbonmaterialscanbeclassifiedintothreetypesbasedontheirporesizes:microporous<2nm,2nm50nm.合成方法Adv.Mater.2006,18,2073–
3、2094介孔碳材料Meso-porouscarbonmaterialsareveryimportantforapplicationsinvolvinglargemolecules,suchasadsorbentsfordyes,catalystsupportsforbiomolecules,andelectrodesforbiosensors.J.AM.CHEM.SOC.9VOL.131,NO.12,20094543納米微反應(yīng)器ChemicalEngineeringScience66(2011)
4、5366–5373借助微通道反應(yīng)器的特點(diǎn)進(jìn)行的化學(xué)反應(yīng)的改進(jìn)AppliedCatalysisB:Environmental102(2011)232–242Adv.Synth.Catal.2005,347,225–230Ureas液相實(shí)驗(yàn)數(shù)據(jù)bca:氫氣還原b:催化劑的酸中心2倍c:反應(yīng)時(shí)間為2hCnts有可能阻礙了酸中心使得反應(yīng)轉(zhuǎn)化率明顯降低;引入TEOs凝膠,反應(yīng)轉(zhuǎn)化率較低,選擇性40%左右,是在最近設(shè)計(jì)得到的固體催化劑中最高的。可能的原因是像文獻(xiàn)里所說(shuō)凝膠起到了微通道的效果。CatalLet
5、t(2009)129:20–25Meso-porous固定床數(shù)據(jù)交換4次后浸漬法添加助劑Ce,Sn,Gr,Al,Zn