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《SBT類鈣鈦礦結(jié)構(gòu)鐵電陶瓷制備與Cu單晶襯底上薄膜沉積探索》由會員上傳分享,免費(fèi)在線閱讀,更多相關(guān)內(nèi)容在學(xué)術(shù)論文-天天文庫。
1、SBT類鈣鈦礦結(jié)構(gòu)鐵電陶瓷制各與Cu單品襯底上薄膜沉積探索關(guān)鍵詞:類鈣鈦礦鐵電濺射靶材SBT鐵電薄膜cu單晶襯底射頻磁控濺射法青島科技人學(xué)研究生學(xué)位論文PREPARATIONOFSBTPEROVSKITE.LIKECERAMICSANDFERROELECTRICTHINFILMSDEPOSITIONONCuⅥ/AFERSABSTRACTRecently,ferroelectricthinfilmsaswellastheirapplicationsinnon—volatileferroelectricrandomaccessmemory(FRAM)arebecom
2、ingresearchhotpoint.However,ferroelectricfatiguehasbeenthemainfactorpreventingthefurtherdevelopmentandwidelyapplicationsofFRAM.Inordertosolvetheproblem,novelmaterialandwafer,suchasfatigue.freeperovskite—likeSrBi2Ta209(SBT)ferroelectricfilmandcoppersinglecrystalwaferareintroduced.Thep
3、reparationofsputteringtargetsanddepositionwafers,aswellasthepreparationofferroelectricthinfilmsarecomprehensivelyexploredinthispaper.SBTceramicsandsputteringtargetswithdifferentBi203additionsaresynthesizedbysolidstatereaction.TheeffectsofsynthesistechniqueandBi203additiononthestructu
4、reandpropertiesofSBTperovskite—likeceramicsareinvestigated.Withas-preparedSBTtargets,SBTfilmsaredepositedoncoppersinglecrystalwafersbyradiofrequencymagnetronsputtering(RMP).Subsequently,thedepositedSBTfilmsareannealedatdifferenttemperaturesatpurenitrogen.ThestructureandpropertiesofSB
5、Tthinfilmsareinvestigated.TheexperimentalresultsindicatethattheoptimalquenchedtemperaturesforBiTa04precursorsandSBTpowdersare900℃and950℃.respectivelyinatwo-stageprocessofSBTsynthesis.AfterI000*Csinteringatypicalperovskite·likestructureSBTcanbeidentified.Thedensityofperovskite—likeSBT
6、ceramics,aswellasthedegreeofc·axispreferredorientationandgrainsizewillbeincreasedobviouslywhenraisingthesinteringtemperature.Furthermore,theferroelectricityincreaseswhilethedielectricitydecreasesasthesinteringtemperaturehigher.TheBi203additionalsoinfluencesthemicrostructure,andincrea
7、sesboththedegreeofC-axispreferredSBT類鈣鈦礦結(jié)構(gòu)鐵電陶瓷制備與Cu單品襯底上薄膜沉積探索orientationandgrainsizeofas.resultSBT.ThedielectricityandferroelectricityalsovaryaccompanyingwiththeBi203addition.AnoptimalferroelectricityCanbeobtainedwhentheBi203additionis5m01%.Theperovskite—likeSBTceramictargetswithdif
8、ferentBi203a