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1、TheChemistryofOrganicSiliconCompounds.Volume2EditedbyZviRappoportandYitzhakApeloigCopyright?1998JohnWiley&Sons,Ltd.ISBN:0-471-96757-2CHAPTER17RecentadvancesinthechemistryofsiliconheteroatommultiplebondsNORIHIROTOKITOHandRENJIOKAZAKIDepartmentofChemistry,GraduateSchoolofScien
2、ce,TheUniversityofTokyo,7-3-1Hongo,Bunkyo-ku,Tokyo113,JapanFax:C81-3-5800-6899I.INTRODUCTION....................................1064A.MultipleBondstoSilicon............................1064B.TheoreticalCalculations..............................10651.Silanonesandsilanethiones.
3、........................10652.Otherdoublebondstosilicon........................10673.Miscellaneous..................................1067II.DOUBLEBONDSBETWEENSILICONANDGROUP16ELEMENTS........................................1068A.Introduction...................................
4、...1068B.SiliconOxygenDoubleBonds(Silanones).................10681.Formationfromhydrosilanes........................10682.Formationfromcyclicsilylethers.....................10693.Formationfromallyloxysilanederivatives................10714.Formationfromsilanolderivatives.....
5、................10745.Formationfromsilylenes...........................10756.Formationfromsilenesandsiliconheteroatomdouble-bondcompounds.....................................1080C.SiliconSulfurDoubleBonds(Silanethiones)................10831.Formationfromhydrosilanes.........
6、................10842.Formationfromdiaminosilanes........................10863.Formationfromsilylenes............................10864.Formationfromsilicon-containingcyclicpolysul?des.........10905.Formationfromadisilene...........................10946.Formationfromthioketen
7、es..........................10957.MatrixisolationofSiS2,Cl(H)SiDSandCl2SiDS..........109610631064NorihiroTokitohandRenjiOkazakiD.SiliconSeleniumandSiliconTelluriumDoubleBonds(SilaneselonesandSilanetellones).................................10971.Transientsilaneselones........
8、.....................10972.Silaneselonederivedfromsilicocene...............
