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1、2014年2月Vol.32No.2February2014ChineseJournalofChromatography107~116專論與綜述DOI:10.3724/SP.J.1123.2013.10002金屬有機框架材料的研究進展1,222222翟睿,焦豐龍,林虹君,郝斐然,李佳斌,顏輝,2222?2?李楠楠,王歡歡,金祖耀,張養(yǎng)軍,錢小紅(1.北京工業(yè)大學(xué)生命科學(xué)與生物工程學(xué)院,北京100022;2.蛋白質(zhì)組學(xué)國家重點實驗室,北京蛋白質(zhì)組研究中心,軍事醫(yī)學(xué)科學(xué)院放射與輻射醫(yī)學(xué)研究所,北京102206)摘要:金屬有機框架(metal?organicframeworks,MOFs)材料
2、是一類由有機配體與金屬中心經(jīng)過自組裝形成的具有可調(diào)節(jié)孔徑的材料。與傳統(tǒng)無機多孔材料相比,MOFs材料具有更大的比表面積,更高的孔隙率,結(jié)構(gòu)及功能更加多樣,因而已經(jīng)被廣泛應(yīng)用于氣體吸附與分離、傳感器、藥物緩釋、催化反應(yīng)等領(lǐng)域中。新興材料的出現(xiàn)極大地促進了各個學(xué)科間的相互發(fā)展,本文綜述了近年來MOFs材料的研究發(fā)展,包括MOFs材料自身的特點、國內(nèi)外發(fā)展現(xiàn)狀、應(yīng)用領(lǐng)域以及復(fù)合MOFs材料的研究熱點,并對今后的發(fā)展進行了展望。關(guān)鍵詞:金屬有機框架;配位聚合物;多孔材料中圖分類號:O658文獻標識碼:A文章編號:1000?8713(2014)02?0107?10Progressinmetal?
3、organicframeworks1,222222ZHAIRui,JIAOFenglong,LINHongjun,HAOFeiran,LIJiabin,YANHui,2222?2?LINannan,WANGHuanhuan,JINZuyao,ZHANGYangjun,QIANXiaohong(1.CollegeofLifeScienceandBio?Engineering,BeijingUniversityofTechnology,Beijing100022,China;2.StateKeyLaboratoryofProteomics,BeijingProteomeResearchCe
4、nter,BeijingInstituteofRadiationMedicine,Beijing102206,China)Abstract:Metal?organicframeworks(MOFs)areaclassofcrystallinematerialsbuiltfromorganicbindingligandsandmetalionsthroughself?assembly.Currently,MOFshavedrawnagrowinginterestamongthescientificteamsofvariousfields.Comparedwithconventionali
5、nor?ganicporousmaterials,MOFspossesslargerspecificsurfaceareas,higherporosityanddiversi?tyofstructuresandfunctions,thusmanypotentialapplicationshavebeenproposedinthedomainsofgasadsorptionandseparation,sensors,drugdelivery,catalysisorothers.ThecombinationsofMOFsandothermaterialssuchasgrapheneoxid
6、e,magneticnanoparticleshaveobviousadvantagesinadsorptionandseparation.Theappearanceofnovelmaterialsgreatlypromotesinterdisciplinarydevelopmentssuchasorganicchemistry,inorganicchemis?try,coordinationchemistry,materialschemistry,lifescienceandcomputerscience.Thisarti?clereviewstheprogressofMOFsinr
7、ecentyears,includingthecharacteristicsofMOFs,advancesathomeandabroad,applications,centralissuesofcompoundMOFsandthepros?pectsinthefuture.Keywords:metal?organicframeworks(MOFs);coordinationpolymers;porousmaterials金屬有機框架(metal