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1、礦物巖石地球化學(xué)通報(bào)·非常規(guī)油氣資源·BulletinofMineralogy，PetrologyandGeochemistryVo1．34No．1，Jan．，2015頁(yè)巖油資源定量評(píng)價(jià)中關(guān)鍵參數(shù)的選取與校正以松遼盆地北部青山口組為例薛海濤，田善思，盧雙舫，張文華，杜添添，穆國(guó)棟21．中國(guó)石油大學(xué)(華東)，山東青島266580；2．東北石油大學(xué)，黑龍江大慶163318摘要：頁(yè)巖油資源評(píng)價(jià)過程中，常用熱解參數(shù)(S。)反映含油性。由于實(shí)驗(yàn)關(guān)系，所測(cè)得的s．存在輕烴、重?zé)N的損失，為更準(zhǔn)確的對(duì)頁(yè)巖油資源進(jìn)行定量評(píng)價(jià)，本文通過有機(jī)質(zhì)成烴動(dòng)力學(xué)研究以及對(duì)樣品抽提前后的熱解參數(shù)進(jìn)行對(duì)比，對(duì)s．進(jìn)行輕、
2、重?zé)N補(bǔ)償校正，獲得泥頁(yè)巖總含油率參數(shù)，根據(jù)泥頁(yè)巖排烴門限確定其可動(dòng)油含量參數(shù)(S／TOC)。研究結(jié)果表明，松遼盆地北部青山口組泥頁(yè)巖s，校正前后相差2—3倍，排烴門限對(duì)應(yīng)的S。／TOC=75mg／gTOC，結(jié)合黏土礦物含量(表征可壓裂性)，優(yōu)選出頁(yè)巖油勘探開發(fā)有利區(qū)：青一段有利區(qū)主要集中在齊家古龍凹陷中北部及龍虎泡大安階地中部，青二、三段集中在龍虎泡大安階地中部與齊家古龍凹陷中南部。關(guān)鍵詞：頁(yè)巖油；含油率；S校正；可動(dòng)量參數(shù)的選??；有利區(qū)中圖分類號(hào)：P618．12文章編號(hào)：1007-2802(2o15)01-0070．09doi：10．3969／j．issn．1007．2802．2015
3、．o1．008SelectionandVerificationofKeyParametersintheQuantitativeEvaluationofShaleOil：ACaseStudyattheQingshankouFormation，NorthernSongliaoBasinXUEHai．tao，TIANShan．si，LUShuang．fang，ZHANGWen．hua'2DUTian—tian'2MUGuo—dong'1．ChinaUniversityofPetroleum(EasternChina)，QingdaoShandong266580，China；2．Northeas
4、tPetroleumUniversity，DaqingHeilongjiang163318，ChinaAbstract：Pyrolysisparameter，S1，isakeyparameteronbehalfofoilcontentintheshaleoilresourceevaluationprocess．ButcontentsoflighthydrocarbonsandheavyhydrocarbonsinthemeasuredSlwereunderestimatedbecauseoftheexperi—mentalprocess．Inordertoaccurateevaluate
5、shaleoilresources，weconductedrockpyrolysisexperimentsonoriginalandextractedsamplesofchloroformbitumen“A”．thencomparedtheirresultstoacquirethecompensationfactorsofheavyhy—drocarbonsforS1andtodeterminethecompensationfactorsoflighthydrocarbonsofSl，bysuchwegainedtheoilcontentofshale，whichwecalledthec
6、alibratedS】．Moreover，wedeterminedtheflowingamountofshaleoilaccordingtothehy—drocarbonexpulsionthreshold．ResultsshowedthattheoriginalS1andthecalibratedS1aresignificantlydifferent，andthatthethresholdis75mg／gTOC．Thefavorableareaofexplorationanddevelopmentcanbeselectedaccordingtoresourcee—valuationso
7、fshaleoilandclayminerals．ThefavorableareasofqnlshouldbeconcentratedinthecentralandnorthernQi—jia—GulongsagandthemiddleoftheLonghupao—Daanterrace，whilethoseofqn2andqn3shouldbemainlyconcentratedinthecenterandsouthernofth
