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《微量添加Fe元素對(duì)CuZrAl塊體金屬玻璃的結(jié)構(gòu)和力學(xué)性能的影響.pdf》由會(huì)員上傳分享,免費(fèi)在線閱讀,更多相關(guān)內(nèi)容在應(yīng)用文檔-天天文庫(kù)。
1、TransaefionsofNonferrousMetals愛Avai:la三bleo,nSlinecaitewwnwc.secieDnceidrierect.ctomSocietyofChinaTrans.NonferrousMet.Soc.China22(2012)1123—1126www.tnmsc.CnEffectofminor-additionofFeonstructuralandmechanicalpropertiesofCuZrA1bulkmetallicglassxuHong.wei’。,DUYu.1eiI_,DE
2、NGYu。1.EngineeringResearchCenterofMaterialsBehaviorandDesignofMinistryofEducation,SchoolofMaterialsScienceandEngineering,NanjingUniversityofScienceandTechnology,Nanjing210094,China;2.JiangsuInstituteofAdvancedMaterials,Danyang212300,China;3.NationalLaboratoryofSolidSt
3、ateMicrostructuresandCenterforMaterialsAnalysis,NanjingUniversity,Nanjing210093,ChinaReceived19September2011;accepted12January2012Abstract:TheCuZrAlbulkmetallicglasswithminor-additionofFewaspreparedbyrapidquenchingmethod.ThestructureswereexaminedbyX—raydifraction(XRD)
4、.TheefectofFeontheglass-formingabilitywasstudiedbydiferentialscanningcalorimetry(DSC).Theminor.a(chǎn)dditionofFeobviouslyextendsthesupercooledliquidregionATx.TheplasticstrainoftheCu44Zr4sA17Febulkmetallicglassisabout1.5%.Themicrostructureswereexaminedbytransmissionelectron
5、microscopy(TEM).Itisfoundthatwhen1%一2%Fe(molefraction)wereintroducedintotheCuZrA1alloymatrix,nanoscalephaseseparationoccursintheas—preparedCu44Zr48A17Febulkmetallicglass.Keywords:bulkmetallicglass;microstructure;mechanicalproperty;phaseseparation;Feadditionshearbands,
6、andobviousimprovementoftheplasticity.1IntroductionInthepresentwork,Cu44Zr48A17FeBMGwasprepared,theefectsofFeontheGFAandplasticitywerestudied,Itiswellknownthatbulkmetallicglasses(BMGs)andthemicrostructureswereexaminedbyTEM.exhibituniquemechanicalproperties,suchashighst
7、rengthandelasticlimit.excellentcorrosionresistance2Experimental[1,2],butlimitedroomtemperatureplasticity【3].ItwasreportedthattheroomtemperatureplasticityofBMGsAlloyingotswithnominalcompositionofcanbeimprovedbyintroducingdendriticandsphericalCu44Zr48AI7Fewerepreparedfr
8、omelementalmetalsbcccrystallinephase[4,5],nano—sizedcrystallinephase(purity>99.9%、byarc—meltingunderaTigetteredAr[6]intothea