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1、上海大學碩士學位論文(2005)摘要用銅模吸鑄法制備出新型DyGdCoAI和YDyCoAl大塊金屬玻璃,用DSC和DTA等方法研究了其熱穩(wěn)定性,用XRD方法以及Miedema模型和原子鍵參數(shù)等分析了其玻璃形成能力,并研究了DyGdCoAl大塊金屬玻璃的磁熱效應。結果發(fā)現(xiàn),隨著Gd含量的增加,Dy56。Gd。C020A124合金的熱穩(wěn)定性降低,玻璃形成能力則是先升高后降低;隨著Al含量的增加,Y31Dy49。C020Al:,合金的熱穩(wěn)定性呈上升趨勢,而玻璃形成能力則在Al含量為x=24~26左右較大;Co含量對二個合金系的熱穩(wěn)定性和玻璃形成能力的影響
2、也相似,最佳Co含量在x=20左右,即Dy3IGd25C020A124和Y31Dy25C020A124玻璃形成能力較大。用低熔點的ce和Sm分別代替Y3lDy25C020A124合金中的Dy,發(fā)現(xiàn)Y3lDy25c020A124、Y31Sm25C020A124和Y31Ce25C020A124三種合金的熱穩(wěn)定性下降,而其玻璃形成能力則上升;Ni元素代替Gd3lDy25C020A124和Dy3lGd2sc020A124中的部分co元素,會導致金屬玻璃Gd31Dy25ColoNiloAl24和Dy31Gd25ColoNiloAl24的過冷液相區(qū)△t下降。D
3、yGdCoAl合金具有一定的磁熱效應,可以通過調(diào)整合金組元的成分來改變其居里溫度和磁熱效應。關鍵詞:大塊金屬玻璃過冷液相區(qū)熱穩(wěn)定性玻璃形成能力磁熱效應上海大學碩士學位論文(2005)ABSTRACTNovelbulkmetallicglassesYDyCoAIandDyGdCoAlwerepreparedbysuctioncastingmethodusingacoppermoldunderAratmosphere.TheirthermalstabilitywereinvestigatedbymeansofDSCandD’FA.Formationan
4、dglass—formingabilityoftheNloyswerestudiedbyXRDandanalyzedbyMiedema’Smodelandatomicbondparameters.TheresultsshowthatthethermalstabilityoftheDy56。G文C020A124alloysdecreasewiththeincreaseofXwhiletheglass—formingabilityincreasesatfirstandthendeclines.TheinfluenceofA1onthethermalst
5、abilityandglass—formingabilityofYDyCoAlissimilartothoseofDyGdCoAIalloys.ThethermalstabilityisimprovedwithincreasingxintheY3tDy49-xC020A1zalloysandtheglass—formingabilityisbetterwhenxisintherangeof24-26.TheinfluenceofCoonthethermalstabilityandglass.formingabilityoftheYDyCoAIiss
6、imilartothoseofDyGdCoAlalloys.Asaresult,Y3IDy25C020A124andDy31Gd25C020A124alloyshavealargerglass-formingability.Thethmraalstabilitydeclineswhiletheglass—fomfingabilityincreasesforY31Dy25C020A124,Y3JSm25C020A124andY3ICe25C020A124;ThatNireplacedpartiallyCointheGd3lDy25C020A124an
7、dDy31Gd2sC020A124alloysresultsinadecreaseofthesuper—cooledliquidregion△t.DyGdCoAIalloyshavemagnetocaloriceffectandtheneeded兀(Curietemperature)and4Tad(adiabatictemperaturechange)canbeobtainedbychangingtheCOritentsofelementssuchasGdorC0.Keywords:Bulkmetallicglass,Supercooledliqu
8、idregion,ThermalstabilityGlass—formingability,Magnetoealorice