atomic structure notes:原子結(jié)構(gòu)的筆記

atomic structure notes:原子結(jié)構(gòu)的筆記

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時間:2019-02-21

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1、AtomicStructureNotesAdaptedfromtheScienceHelponLine(E.Muniz/G.Maynes)I.DevelopmentoftheAtomicTheory?DemocritusmaynothavebeenthefirstoftheancientGreekstosuggestanatomictheory,thisdistinctiongoestohisteacherLeucippus,buthisnameisoftenassociatedwiththefirstatomictheory,becauseofhis

2、supportofit.ToDemocritus,atomswerecompletelysolid,homogeneous,indestructibleobjects.?JohnDalton,anEnglishchemist,mightbecalled"thefatherofthemodernatomictheory.".Duringtheearly1800’s,Dalton’sinterestsinMeteorologyandgasesledhimtoreadtheworksofAntoineLavoisierandJosephProust.Lavo

3、isierhadstatedthelawofconservationofmass:thatthemassofmaterialsbeforeachemicalreactiontakesplaceisexactlyequaltothemassofthematerialsafterthereactioniscompleted.Prousthadobservedthelawofdefiniteproportions,statingthattheproportionbymassoftheelementsinagivencompoundisalwaysthesam

4、e.Daltonfeltthatthefindingsofthesemengavestrongsupporttotheideaofatoms.HeformulatedanatomictheorythatwouldincludetheobservationsmadebyLavoisierandProust.Dalton’sAtomicTheory1)Allelementsarecomposedofatoms,whichareindivisibleandindestructibleparticles.2)Allatomsofthesameelementar

5、eexactlyalike;inparticular,theyallhavethesamemass.3)Allatomsofdifferentelementsaredifferent;inparticular,theyhavedifferentmasses.4)Compoundsareformedbythejoiningofatomsoftwoormoreelements.Inanycompound,theatomsofthedifferentelementsinthecompoundarejoinedinadefinitewhole-numberra

6、tio,suchas1to1,2to1,3to2,etc.?JosephJohnThomsonsubjectedcathoderaystomagneticandelectricfieldsandshowedthatthebeamwasdeflectedaswouldbeexpectedfornegativelychargedparticles.Hecalculatedtheratiooftheelectron’schargetoitsmass.OnApril30,1897,Thomsonannouncedthatthecathoderaysconsis

7、tedofnegativelychargedparticles,whichrepresentedfundamentalparticlesofmatter.Hewasnotthefirstpersontosuggestthattheseparticlesexisted,nordidhecointheterm"electron".Yetheisgenerallycreditedwiththediscoveryoftheelectron.HewasawardedwiththeNobelPrizeinPhysicsin1906.?J.J.Thomsonisal

8、sorememberedforhis"plum-pudding"modeloftheatom,

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