資源描述:
《Surface Enhanced Raman Scattering Spectroscopy.pdf》由會員上傳分享,免費(fèi)在線閱讀,更多相關(guān)內(nèi)容在學(xué)術(shù)論文-天天文庫。
1、TermpaperforPhysics598OSSurfaceEnhancedRamanScatteringSpectroscopyMaterialsScienceandEngineeringDepartment,UniversityofIllinois,Urbana,61801,ILShanJiang,sjiang2@uiuc.eduAbstractThisreviewcoversfromthebasicprinciplesofRamanspectroscopytotheadvancedtechniqueofsurfaceenhanced
2、RamanScattering(SERS)spectroscopy.AfterbrieflygoingthroughthedescriptionofRamanandintroductionofthedevelopmentofSERS,thearticlewillfocusonthe“hotspot”ofthecurrentresearchworkonSERS–singlemoleculespectroscopy.Wewillseelaterthat“hotspot”isalsofrequentlyusedtodescribetheplace
3、whereSERShappens.Thisvaguedescriptioninsomeextentreflectstheambiguityandcontroversyintheunderstandingofthephenomenon.However,singlemoleculeSERSprovidesusapossiblewaytodisclosethesecret.Singlemoleculespectroscopyisnotonlyanoveltooltoexplorethepropertiesofthemolecules;italso
4、shineslightonthefurtherunderstandingtheSERSitself.Researchworkfromseveralgroupsinthisfieldwasintroduced.TherearelotsofotherapplicationsforSERSinthebioscience,whichisbeyondthescopeofthisshortpaper.OnlytheapplicationofSERSstudyingthesurfaceadsorptionanddetectionofDNAandRNAwe
5、representedtogivesomeflavorsinthisresearchfield.Finally,whatcanwedowithSERS?Inthelastpartofthepaper,thetopicofdoingSERSontheflatsurfacewasdiscussed.Thisisnotonlyofintellectualfun,butmayalsogiveusgreatadvantagestodevelopnewtechniques.OneexampleistocombinetheSERSwithsurfacef
6、orceapparatus(SFA)study,whichrequirestwosmoothflatsurfaces.Unfortunatelysmoothflatsurfaceisthekilleroftheenhancement.Thenherewetrytorescue.OnlylittlemathematicswasgivenfortheillustrationoftheprinciplesofRaman.TheelectromagneticexplanationofSERSwilldefinitelybedemonstratedb
7、etterwithequations,whichhoweverfallsbeyondmybackgroundandknowledge.Atlast,tworeferencesarestronglyrecommendedtothosewhowantagoodintroductorybutnottooout-of-datematerial.OneisthehandoutforMITclassbyKatrinKneipp.SheisoneoftheearliestresearcherswhoworkonthesinglemoleculeSERS.
8、Anotherisafreeonlinejournalcalled“theinternetjournalofvibrationalspectroscopy”withafeatur