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1、METHOD8070ANITROSAMINESBYGASCHROMATOGRAPHY1.0SCOPEANDAPPLICATION1.1Method8070isagaschromatographic(GC)methodapplicabletothedeterminationofnitrosamineinaqueousmatricessuchasgroundwaterandmunicipalandindustrialdischarges.Itisalsoapplicabletosolidmatricessuchassoils,sediments,andsl
2、udges.Specifically,thismethodcoversthedeterminationofthefollowingcompounds:AppropriateTechniqueaCompoundCASNo.351035203540/135503580N-Nitrosodimethylamine62-75-9XXXXXN-Nitrosodiphenylamine86-30-6XXXXXN-Nitrosodi-n-propylamine621-64-7XXXXXaChemicalAbstractServiceRegistryNumber.XG
3、reaterthan70percentrecoverybythispreparationtechnique.1.2Themethoddetectionlimit(MDL)foreachanalyteofinterestislistedinTable1.TheMDLforaspecificwastewatermaydifferfromthoselisted,dependinguponthenatureofinterferencesinthesamplematrix.Thismethodhasbeentestedforlinearityofrecovery
4、fromspikedorganic-freereagentwaterandhasbeendemonstratedtobeapplicablefortheconcentrationrangefrom4xMDLto1000xMDL.1.3Whenthismethodisusedtoanalyzesamplesfrommatricesthatarenotwellcharacterized,compoundidentificationsshouldbeconfirmedbyatleastoneadditionalqualitativetechnique.Sec
5、ondaryconfirmationcanbeperformedusingadissimilarGCcolumn,specificelementdetector,ormassspectrometer(MS).1.4Thetoxicityorcarcinogenicityofeachreagentusedinthismethodhasnotbeenpreciselydefined.However,eachchemicalcompoundshouldbetreatedasapotentialhealthhazard.Fromthisviewpoint,ex
6、posuretothesechemicalsmustbereducedtothelowestpossibleconcentrationbywhatevermeansavailable.ThelaboratoryisresponsibleformaintainingacurrentawarenessfileofOSHAregulationsregardingthesafehandlingofthechemicalsspecifiedinthismethod.Areferencefileofmaterialsafetydatasheetsshouldals
7、obemadeavailabletoallpersonnelinvolvedinthechemicalanalysis.1.5Thesenitrosaminesareknowncarcinogens.Therefore,utmostcaremustbeexercisedinthehandlingofthesematerials.Nitrosaminereferencestandardsandstandardsolutionsshouldbehandledandpreparedinaventilatedgloveboxwithinaproperlyven
8、tilatedroom.1.6N-Nitrosodiphenylamineisreported
