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1、河南科技大學(xué)畢業(yè)設(shè)計(jì)(論文)鑄造多晶硅晶體生長速率對(duì)雜質(zhì)分布的影響研究摘要目前,鑄造多晶硅是最主要的光伏材料,其結(jié)晶組織、缺陷、和雜質(zhì)含量顯著影響著太陽能電池的轉(zhuǎn)換效率。雜質(zhì)的濃度和分布是影響光電轉(zhuǎn)換效率的重要因素。由于多晶硅錠的質(zhì)量好壞主要取決于長晶過程中的固液界面形狀及晶體生長速率大小,固液界面形狀及晶體生長速率大小對(duì)定向凝固的排雜效果起決定作用,一般認(rèn)為微凸的固液界面更有利于多晶硅雜質(zhì)和位錯(cuò)的排除。因此深入研究多晶硅生長速率對(duì)雜質(zhì)分布的影響,分析它對(duì)多晶硅錠結(jié)晶學(xué)及電學(xué)性能的影響,不僅有利于生長出高成品率的鑄造多晶硅錠,而且可以降低鑄造多晶硅硅片的制造成本。本工作利用微波光電導(dǎo)
2、衰減儀(μ-PCD)、二次離子質(zhì)譜儀(SIMS),以及紅外掃描儀(IR)等方法對(duì)鑄造多晶硅的雜質(zhì)以及少子壽命的分布進(jìn)行了系統(tǒng)的研究。實(shí)驗(yàn)發(fā)現(xiàn),硅錠中的氧濃度隨硅錠高度的增加而逐漸降低,而碳的分布情況正好相反。研究發(fā)現(xiàn),在低速凝固條件下雜質(zhì)的排除效果很好,平均少子壽命較高,但多晶硅錠的紅區(qū)較長,鑄錠周期長。而高速凝固雜質(zhì)的排除效果不佳,硅錠紅區(qū)較短,但平均少子壽命較低。實(shí)驗(yàn)發(fā)現(xiàn)多晶硅錠晶體生長速率1.5cm/h為工業(yè)生產(chǎn)中較優(yōu)長晶速率。關(guān)鍵詞:鑄造多晶硅,雜質(zhì),少子壽命,長晶速率23河南科技大學(xué)畢業(yè)設(shè)計(jì)(論文)Theinvestigationonthecrystalgrowthrate
3、ofcastingpolycrystallinesiliconinfluencingonthedistributionofimpurityABSTRACTAtpresent,castingpolycrystallinesiliconisthemainPVmateril.Itaffectsaretheimportantfactorsofphotoelectricconversionefficiency.becausequalityofpoolycrystallinesiliconingotsisdeterminedbythepositionofthesolid/liquidinterf
4、aceandgrowthrateofcrystal.Theshapeofsolid/liquidinterfaceandgrowthratedeterminedthequalityofrejectingofimpurity.Generally,smallprotrudingliquid-solidinterfaceismoreadvantageoustotherejectofdislocationandimpuritry.Sofurtherresearchontheinfluenceofpolysilicongrowthrateontheimpuritydistributionand
5、electricalbehaviourofpolycrystallinesiliconingotswillhelpusimprovetheyieldoftheingotsandreducethecostofcastingpolycrystallinesilicon.Inthisthesis,weinvestigatethedistributionofimpurityandminoritycarrierlifetimeoftheingotsbyMicrowavephotoConductiveDecay(μ-PCD),ScanningInfraredMicroscopy(IR),Scan
6、ningInfraredMicroscopy(SIRM).Intheexperiments,oxygencontentincreasesinveticaldirection,Whilecarbondistributionisexactlythepposite.Wefindthatlow-speedsolidificationconditionsisgoodtotherejectofalltherejectofallthemetalinpurity,minoritycarrierlifetimeishigher,butthecastingcycleislonger.WhleHigh-s
7、peedsolidificationtothedisadvantageoftherejectofimpurity.anditsminoritycarrierlifetimeislowerExperimentshavefoundthatpolyingotgrowthratefor1.5cm/hforindustrialproductionisabetterchoice.KEYWORDS:castingpolycrystallinesilicon,impuri