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1、重慶大學(xué)碩士學(xué)位論文降溫法生長(zhǎng)KDP晶體的實(shí)驗(yàn)和數(shù)值模擬姓名:毛琨申請(qǐng)學(xué)位級(jí)別:碩士專(zhuān)業(yè):工程熱物理指導(dǎo)教師:李明偉20070420重慶大學(xué)碩士學(xué)位論文英文摘要ABSTRACTKDPcrystal,asonekindofnon-linealopticalmaterialwimgoodqualities,hasbeenappliedwidelytothehi曲technologyfieldssuchaslaserfrequencyconversion,elcctroopticalmodulation,opticswitchandSOon.Big—sizedKDPcrystalist
2、hepreferredmaterialforICF(thermalConfinemcmtFusion),othermaterialswithbettercomprehensiveperformancecomparedwithKDPcrystalCannotbegaineduptillnow.Becauseofitsspreadingusageinthesefields,morehigh—qualityKDPcrystalisurgentneeded.WiththedevelopmentofICFtechnology,USAprohibitstheexportofrelativet
3、echnologyandmaterials.Intheinternationalmarketsthebig—sizedandhigh-qualityKDPcrystalfallsintoshortofsupply.ThefocusoftheresearchonKDPcrystalinrecentyearsistryingtoincreaseKDPgrowthrate,shortenitsgrowthcycleanddecreaseitscostatthepreconditiontoassuringitshi曲opticalquality.Themethodoftemperatur
4、ereductionistheusualmethodofKDPcrystalgrowth.Itisveryimportantmaintainingarlappropriaterateoftemperaturereductioninorderthatthesolutionisstayinginmetastablezoneduringtheperiodofgrowth.So,intheprocessofcrystalgrowth,allappropriatesupersaturationofthesolutionneededbeconsideredpivotally.Inthispa
5、per,thefollowingresultshavebeenobtainedbyKDPcrystalgrowthexperimentsandnumericalsimulation.Theimtialtemperatureofsolutionandrateoftemperaturereductionhaveeffectsonthequantityandrateofcrystalgrowth.Solventevaporationwillaccelerategrowthbutloweritsquality.Sothevesselofgrowthsolutionshouldenable
6、closed,growthsolutionshouldbecontrolledappropriatelybytherateoftemperaturereduction.Thestabilityandpurityofthegrowingsolutionhavemorenotableinfluenceongrowthrateandquailty.ThepHvalueofthegrowingsolutionchangesthemorphologyofthegrowncrystal.pH=4.5istheappropriatevalueforKDPcrystalgrowthfromsol
7、ution.Thedistributionofcrystalsurfacesupersaturationtrendsgraduallydecreasedfromtheedgetothecenterpositionofthecrystal.Onthesalneconditions,supersaturationwillbelowerwiththegrowthrateincreasingandsupersaturationwillbeincreasedwiththerotations