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《Modern Organic Synthesis in the Laboratory(1)》由會(huì)員上傳分享，免費(fèi)在線閱讀，更多相關(guān)內(nèi)容在學(xué)術(shù)論文-天天文庫(kù)。
1、ForewordThosewhodonotwanttoimitateanything,producenothing.—SalvadorDaliThereexistsacloseanalogybetweenthetrialsandtribulationsofachemistandthoseofanartisan.Justasanartistmustbalancethesensitiveinterplayofcolor,light,andbrushstroketocreateatimelesspainting,sotoomustthec
2、hemistcarefullymarshalthereagents,solvents,andreactionsthatoccupychemicalspacetosuccessfullyforgeanewmolecularentity.Findingreliable,standardizedproceduresforthoseroutinetransformationsisoftenatime-consumingandtediousprocess,onethatsubtractsfromeffortthatcouldbedevoted
3、towardsmorecreativeandexcitingpursuits.Indeed,muchoftheexcitement,fascination,andallureofsyntheticorganicchemistryresidesintheimaginativeexplorationofnewrealmsinchemicalreactivityandcomplexity,notthesearchforstandardoperationprocedures.InModernOrganicSynthesisintheLabo
4、ratory,Drs.JieJackLi,ChrisLimberakis,andDerekP?umprovideproceduresforthecommontransformationsandprotocolsthatpermeatethetapestryofsyntheticorganicchemistry.Fromguidelinesofproper?ashchromatographytechnique,toproceduresfordryingsolvents,andrecipesforstainingsolutions,al
5、lofthebasic,yetessential,organiclaboratorytechniquesaredescribedindetail.Nearlyalltypesofcommonreactionsforoxidations,reductions,functionalgroupmanipulations,andC–Cbondformationarecovered.Withlittlequestion,thisbookisbeautifullysuitedforpractitionersofthe?eldatalllevel
6、sofstudybecauseofthethoroughselectionofproceduresandalayoutthatisbothwelldesignedandcomprehensive.ContentsForewordviiAbbreviationsandAcronymsxv1FundamentalTechniques31.1Safety!31.2UsefulPreparations51.3Chromatography171.4Crystallization221.5ResidualSolventPeaksinNuclea
7、rMagneticResonance242FunctionalGroupManipulations282.1AlcoholOxidationState282.2KetoneOxidationState392.3AcidOxidationState443Oxidation553.1AlcoholtoKetoneOxidationState553.2AlcoholtoAcidOxidationState683.3Ole?ntoDiol703.4AldehydetoAcidOxidationState763.5HeteroatomOxid
8、ations78AbbreviationsandAcronymspolymersupportBINALHLithium2,2′-dihydroxy-Acacetyl1,1′-binaphthylethoxy-acacacetylace
