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《含苯氧基、聯(lián)萘氧基、偶氮苯氧基均三嗪衍生物制備和表征》由會員上傳分享，免費在線閱讀，更多相關內容在學術論文-天天文庫。
1、福建師范大學碩士學位論文摘要AbstractInthispaper,cyanuricchloridewhichs缸uc嘶containingthreechlorineatomswasusedasthemainrawmaterialfortheprovisionofs-triazinering．Wahthedifferentreactivitiesofthethreechlo血eatomsincyanuricchloride，aseriesofnews．triazineringcompoundswerereceivedbythestep-wisereactionthr
2、oughthecontrollingofthetemperature．Thes觚ctureofthesecompoundswerecharacterizedbyElementalanalysis，IR，1HNMRandotherresearchmethods，alsothesolubility,thermalstabilitypropertieswerestudied．Itcanbesummarizedasfollows．1．Withcyanuricchlorideandp-nitrophenolastherawmaterials，2,4，6-3-p—nitroph
3、enoxy-1，3，5-triazineWaspreparedbycontrollingofreactiontemperatureinacetoneandwater．Threedifferentmethodswereusedfornitroreductiontoobtain2,4，6．一aminophenoxy-1，3，5一triazine．Withelementalanalysis，1H-NMR,IR,TGcharacterizationtheproductsobtained，2,4，6—3-P—nitrophenoxy-1，3，5一tfiazineshowsgo
4、odthermalstabilitywhichtheinitialdecompositiontemperaturewasat430"C．Pd／12hydrazinecatalystsystemshowsagoodresultinthreekindsofreductionmethods．2．Witheyanuricchlorideand1，1’BINOLastherawmaterials，NaOHasbase，cetyltrimethylammoniumbromideasphasetransfercatalyst,poly2-chloro-4—1，l’-binapht
5、hyloxy-1，3，5-triazinewerepreparedthroughinterracialpolymerization．Itsstructurewascharacterizedusinguv,IR,1H—NMR,RF,GPC．Alsobyatomicforcemicroscope(AFM)，thesurfaceofthepolymerfilmWasobserved．3．PCCABwasabtainedbythereactionofcyanuricchlorideand4，4’-hydroxyazobenzeneusinginterfacialpolyme
6、rization．DIATOBw豳gotbythereactionof2-Anilino·4，6一dicholoride·1，3，5一traizineand4,4'-hydroxyazobenzeneat40"CinthesolventofacetoneandWater．FTIR,1HNMR,TGDSC，UVwereusedtocharacterizethestructures．AndtheopticlresponsepropertyofDIATOBWasstudiedbyUV二Ⅵs．Alsothesolubilityofthetwoproductswerestud
7、ied，PCCABwon’tdissolveeveniIlDMF，butDIATOBcanbedissolvedinmostkindsofsolvent．III■-L●。；●J福建師范大學碩士學位論文Keywords：Cyanuricchloride,dendrimer,binaphthol，azobenzene，interracialpolymerization，functionalmaterials，s·triazinederivativesIV^中文文摘三聚氯氰具有特殊的結構和反應特性，與三嗪環(huán)相連的3個氯原子具有不同的反應活性，可在不同的反應溫度及pH下
